柴北缘都兰地区含石榴石、蓝晶石片麻岩的变质演化历史     

于胜尧  张建新  宫江华  李云帅 《岩石矿物学杂志》2014,33(3):441-457

在柴北缘超高压变质带东段,新识别出一个高压麻粒岩单元,其主要的岩石组合包括基性（长英质）高压麻粒岩、花岗质片麻岩、富铝质片麻岩（片岩）、石榴角闪岩和英云闪长岩。岩相学和变质反应序列、矿物化学和温压估算结果表明,蓝晶-石榴-黑云-二长片麻岩共经历了4阶段的变质演化：Ⅰ早期进变质阶段,以石榴石核部发育的黑云母、白云母、斜长石和石英等矿物包裹体为特征;Ⅱ峰期高压麻粒岩相阶段,矿物组合为石榴石+蓝晶石+条纹长石+斜长石+石英,金红石Zr温度计和GASP压力计限定其峰期温压条件为：t=800～840℃和p=1.4～1.6GPa;Ⅲ高角闪岩相退变质阶段,矿物组合为石榴石（边部）+黑云母+长石+石英;Ⅳ晚期低角闪岩相-绿片岩相退变质阶段,以蓝晶石周围出现的Ms+Pl±Zo和Mrg+Qtz±Ms±Pl后成合晶为特征。锆石LA-ICP-MSU-Pb定年结果指示高压麻粒岩相变质时代为431Ma。蓝晶-石榴-黑云-二长片麻岩具有顺时针的pt演化轨迹,与基性高压麻粒岩形成于相同的动力学过程。  相似文献   

四川宣汉盘龙洞长兴组白云岩组构定向与统计特征及其成因意义     

赵锐  吴亚生  姜红霞  刘丽静 《地质学报》2014,88(6):1093-1105

四川盆地东北部发育的长兴组礁滩相白云岩层是油气勘探的重点对象,盘龙洞剖面是四川盆地发育最好的长兴组露头,其成岩作用研究对于认识川东北长兴组储层的形成演化控制因素具有很强的借鉴作用。白云岩的组构和产状包含了成因信息,笔者根据薄片观察发现白云石交代结构可分为"均一"与"不等晶"交代两种类型,过渡关系与阴极发光观察结果均表明细中晶是由粉晶发育而来的,且细中晶白云石具"组构定向"现象。首次对该地区白云岩的组构进行了定量统计。统计结果表明,细中晶白云石粒径大小和含量在纵向上有明显的变化规律,含量自上而下减少、粒径变小。结合成岩作用、流体包裹体、阴极发光研究结果综合分析后认为:白云石化作用开始于成岩早期,白云化流体具有低温、高盐度的特点,白云化流体自上而下运移。  相似文献   

四川盆地东部下古生界页岩储集空间特征及其对含气性的影响   总被引：3，自引：0，他引：3  

余川  聂海宽  曾春林  程礼军  邵晓州 《地质学报》2014,88(7):1311-1320

四川盆地东部下古生界海相页岩是一套有利的页岩气储层,通过野外泥页岩剖面及井下岩芯观察、电镜扫描、常规物性及微孔隙结构测试、等温吸附实验等技术方法,对页岩气储层空间特征进行了研究分析,发现下古生界页岩的孔隙可分为三大类六小类,裂缝可分为两大类五小类,具有颗粒细小、致密、大孔发育少、微孔发育多、具有一定孔隙度、渗透率小、喉道细、连通性差的特征。页岩总孔体积主体是由孔径小于200nm的微孔隙提供的,纳米级孔隙和微裂缝是页岩主要的储集空间,页岩有机质孔对于孔隙度具有一定贡献,是富有机质页岩的主要微孔隙类型。页岩的微孔隙结构决定了页岩气的赋存状态和流动方式,孔缝发育程度在一定程度上决定了页岩的含气性及其渗透性能,但大型或巨型裂缝的发育,将给页岩气的有效保存带来破坏。有机质(干酪根和沥青质)和黏土颗粒内的微孔隙表面是吸附态页岩气赋存的主要空间,但有机质孔提供了大部分具吸附性的孔比表面,是控制页岩吸附性能的主要因素,而黏土矿物的作用是次要的。  相似文献   

Geochemical features and origin of natural gas in heavy oil area of the Western Slope,Songliao Basin,China     

Guangyou Zhu  Shuichang Zhang  Barry Jay Katz  Jin Su  Xue Wang  Zihui Feng  Jie Cui  Xingwang Liu 《Chemie der Erde / Geochemistry》2014

The Western Slope of the Songliao Basin is rich in heavy oil resources (>70 × 10⁸ bbl), around which there are shallow gas reservoirs (∼1.0 × 10¹² m³). The gas is dominated by methane with a dryness over 0.99, and the non-hydrocarbon component being overwelmingly nitrogen. Carbon isotope composition of methane and its homologs is depleted in ¹³C, with δ¹³C₁ values being in the range of −55‰ to −75‰, δ¹³C₂ being in the range of −40‰ to −53‰ and δ¹³C₃ being in the range of −30‰ to −42‰, respectively. These values differ significantly from those solution gases source in the Daqing oilfield. This study concludes that heavy oils along the Western Slope were derived from mature source rocks in the Qijia-Gulong Depression, that were biodegraded. The low reservoir temperature (30–50 °C) and low salinity of formation water with neutral to alkaline pH (NaHCO₃) appeared ideal for microbial activity and thus biodegradation. Natural gas along the Western Slope appears mainly to have originated from biodegradation and the formation of heavy oil. This origin is suggested by the heavy δ¹³C of CO₂ (−18.78‰ to 0.95‰) which suggests that the methane was produced via fermentation as the terminal decomposition stage of the oil.  相似文献   

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)     

Nenad Grba  Aleksandra Šajnović  Ksenija Stojanović  Vladimir Simić  Branimir Jovančićević  Goran Roglić  Vladisav Erić 《Chemie der Erde / Geochemistry》2014

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.  相似文献   

Geochemical characteristics and genetic types of crude oils from Qinjiatun and Qikeshu oilfields in the Lishu Fault Depression,Songliao Basin,northeastern China     

Wei Zeng  Haiyu Liu  Min Zhang 《中国地球化学学报》2014,33(1):103-108

The Qinjiatun and Qikeshu oilfields are new Mesozoic petroleum exploration targets in Lishu Fault Depression of Songliao Basin, northeastern China. Currently, researches on geochemistry of crude oils from Qinjiatun and Qikeshu oilfields have not been performed and the genesis of oils is still uncertain. Based on bulk analyses, the crude oils in the Qinjiatun and Qikeshu oilfields of Lishu Fault Depression from the Lower Cretaceous can be classified as three types. TypeⅠoils, from Quantou and Denglouku formations of Qikeshu oilfield, are characterized by high C24tetracyclic terpane/C26tricyclic terpanes ratios, low gammacerance/C30hopane ratios, tricyclic terpanes/hopanes ratios, C29Ts/C29norhopane ratios and 17α(H)-diahopane/17α(H)-hopane ratios, indicating a brackish lacustrine facies. TypeⅡoils, from Shahezi Formation of Qikeshu oilfield show low C24tetracyclic terpane/C26tricyclic terpanes, high gammacerance/C30hopane ratios, tricyclic terpanes/hopanes ratios, C29Ts/C29 norhopane and C30diahopane/C30hopane ratios, thus suggesting that they originated from source rocks deposited in a weak reducing brackish lacustrine environment, or clay-rich sediments. Type oilsⅢ, from some wells of Qikeshu oilfield have geochemical characteristics intermediate between those two types and may be mixture of typeⅠand Ⅱoils.  相似文献   

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis     

Zhigang Yao  Yang Yang  Huawei Ying  Yunpeng Dong 《中国地球化学学报》2014,33(1):119-124

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.  相似文献   

A Spore-Pollen Assemblage from the Damoguaihe Formation in the Tamutsag Basin,Mongolia and Its Geological Implication     

WANG Liyan  WAN Chuanbiao  SUN Yuewu 《《地质学报》英文版》2014,88(1):46-61

Based on the palynological data from Well Ta-19-36 and Well Ta-19-37 in the Ta'nan Sag, and Well Ta-22-1 and Well Ta-21-1 in the Bayin Gobi Sag, a spore-pollen assemblage from the Damoguaihe Formation is named as Cicatricosisporites minutaestriatus- Aequitriradites spinulosus-Protopinus sp. assemblage in the Tamutsag Basin, Mongolia. The assemblage is characterized by abundant gymnosperm pollen and diverse fern spores, counted 46.35%–65.57% and 34.43%–52.58% in percentage respectively. Among the gymnosperm pollen, Pinuspollenites sp.(2.66%–16.94%), Protopinus sp.(0–11.38%) and Protopicea sp.(0–10.81%) are dominant; and Alisporites sp., Cerebropollenites sp., Podocarpidites sp., and Abietineaepollenites sp. are common. Some important elements, such as Chasmatosporites sp., Callialasporites prominulus, Parvisaccites sp., Parcisporites sp., Jiaohepollis cf. annulatus, J. bellus, J. verus, Polycingulatisporites sp., Schizaeoisporites certus, Classopollis annulatus are seen. Within the fern spores, Osmundacidites wellamanii(0.85%–4.93%), Appendicisporites sp.(0–4.45%), Baculatisporites comaumensis(0.80%–2.87%), Cicatricosisporites sp.(0.51%–2.66%), C. minor(0–2.14%), Foraminisporis asymmetricus(0–2.40%), Aequitriradites sp.(0– 2.19%) and Cyathidites minor(0–2.13%) are dominant; and some specie of Densoisporites, Cooksonites, Impardecispora, Pilosisporites, Schizaeosprites, Fixisporites, Leptolepidites, Trilobosporites, Kuylisporites, Klukisporites, Hsuisporites, Couperisporites, Maculatisporites are seen. The angiosperm pollen are rare in the assemblage, characterized by Clavatipollenites sp.(0–0.80%) and Songipollis sp.(0–0.27%). The geological age of the Damoguaihe Formation is assigned to Hauterivian – Barremian of Early Cretaceous according to the palynological data, due to the fact that there existed a lot of diverse spores of the family Schizaeaceae and prosperous gymnosperm saccat pollen which the corpus and sacci are differentiated completely, and the presence of early angiosperm pollen of Clavatipollenites. However, the zircon U-Pb isotopic dating of the volcanic rocks in the Nantun Formation indicated that the overlying strata of the Nantun Formation, i.e. the Damoguaihe Formation must be younger than 127.0±2.0–137.9±1.5 Ma. This is consistent with the palynological data. Furthermore, the vegetation reconstructed on the palynological data of the Damoguaihe Formation is conifer forest with shrubs and grassland, belonging to the semi-humid or humid middle to south subtropical climate. Moreover, three new species, namely Biretisporites punctatus sp. nov., Chasmatosporites reticulates sp. nov. and Concentrisporites contractus sp. nov. are described here.  相似文献   

Paleoclimate and Paleoenvironment of Gonghe Basin, Qinghai-Tibet Plateau, During the Lastdeglacial: Weathering, Erosion and Vegetation Cover Affect Clay Mineral Formation     

SUN Qingfeng  Christophe COLIN 《《地质学报》英文版》2014,88(2):647-660

With the analysis of the sources and formation mechanism of the clay minerals in the sediment core from the Dalianhai lake in the Gonghe Basin,northeastern Tibet-Qinghai Plateau,clay mineral composition proxies,grain-size and carbonate contents have been employed for high-resolution study in order to reconstruct East Asian Summer Monsoon （EASM） over the northeastern Tibet-Qinghai Plateau during the lastdeglacial.The study also extended to establish a relationship between vegetation cover changes and erosion during the last 14.5 ka with pollen record and clay mineral proxies.Smectite/kaolinite and smectite/（illite＋chlorite） ratios allow us to assess hydrolysis conditions in lowlands and/or physical erosion process in highlands of the Gonghe Basin.Before 12.9 Cal ka BP,both mineralogical ratios show low values indicative of strong physical erosion in the basin with a dominant cold and dry phase.After 12.9 Cal ka BP,an increase in both mineralogical ratios indicates enhanced chemical weathering in the basin associated with a warm and humid climate.The beginning of Holocene is characterized by high smectite/（illite＋chlorite） and smectite/kaolinite ratios that is synchronous as with deposition of many peat laminae,implying the best warm and humid conditions specifically between 8.0 to 5.5 Cal ka BP.The time interval after 5.0 Cai ka BP is characterized by a return to high physical erosion and low chemical weathering with dry climate conditions in the basin.Comparing variations of clay mineral assemblages with previous pollen results,we observe a rapid response in terms of chemical weathering and physical erosion intensity to a modification of the vegetation cover in the basin.  相似文献   

Structure and Fluid Transportation Performance of Faults in the Changxing-Feixianguan Formation,Xuanhan County,Northeastern Sichuan Basin     

DU Chunguo  WANG Jianjun  ZHANG Jun  WANG Ping  XUE Mei  ZHOU Huayao 《《地质学报》英文版》2014,88(3):865-877

On the basis of field observations, microscopic thin-sections and laboratory data analysis of ten faults in Xuanhan County area, northeastern Sichuan Basin, central China, the internal and megascopic structures and tectonite development characteristics are mainly controlled by the geomechanical quality in brittle formation of the Changxing-Feixianguan Formation. The fluid transportation performance difference between the faults formed by different geomechanics or different structural parts of the same fault are controlled by the mcgascopic structure and tectonite development characteristics. For instance, the extension fault structure consists of a tectonite breccia zone and an extension fracture zone. Good fluid transportation performance zones are the extension fracture zone adjacent to the tectonite breccia zone and the breccia zone formed at the early evolutionary stage. The typical compression fault structure consists of a boulder-clay zone or zones of grinding gravel rock, compression foliation, tectonite lens, and dense fracture development. The dense fracture development zone is the best fluid transporting area at a certain scale of the compression fault, and then the lens, grinding gravel rock zone and compression foliation zones are the worst areas for hydrocarbon migration. The typical tensor-shear fault with a certain scale can be divided into boulder-clay or grinding gravel rock zones of the fault, as well as a pinnate fractures zone and a derivative fractures zone. The grinding gravel rock zone is the worst one for fluid transportation. Because of the fracture mesh connectivity and better penetration ability, the pinnate fractures zone provides the dominant pathway for hydrocarbon vertical migration along the tensor-shear fault.  相似文献